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Nd ratios on several minerals with a mass spectrometer and then from the slope determine the age of the rock. If a magma cools quickly on the surface of the Earth, some of the Ar may be trapped.
The initial ratio has particular importance for studying the chemical evolution of the Earth's mantle and crust, as we discussed in the section on igneous rocks. If this happens, then the date obtained will be older than the date at which the magma erupted.
If a zircon crystal originally crystallizes from a magma and remains a closed system (no loss or gain of U or Pb) from the time of crystallization to the present, then the Discordant dates will not fall on the Concordia curve.
We could be sure that a mineral containing parentium originally had no daughterium.For example lavas dated by K-Ar that are historic in age, usually show 1 to 2 my old ages due to trapped Ar.Such trapped Ar is not problematical when the age of the rock is in hundreds of millions of years.This is the only way Parentium-123 decays, and there is no other source of Daughterium-123.Furthermore, Parentium and Daughterium are so different in chemical properties that they don't otherwise occur together.